Scattering of light in the presence of nano-structured materials, i.e. with features in the order of the wavelength of the light or smaller, reveals details of how light interacts with matter at... Show moreScattering of light in the presence of nano-structured materials, i.e. with features in the order of the wavelength of the light or smaller, reveals details of how light interacts with matter at the nanoscale. In this dissertation we present four cases of light scattering on nano-structures. First we describe how light confined in 2D structures, namely a dielectric membrane and a metal layer, interacts with either a single nano-hole or a hole-array. Then, we study two cases of light propagating in random scattering media: we show how phase modulation can be used to measure scattering properties in a volume scatterer (e.g. white paint), and we investigate light transport in a rough thin-film silicon solar cell. Show less
We study the technique of photothermal microscopy by which we can detect single nano-objects by their absorption at room temperature. We optimize the sensitivity of this technique and demonstrate... Show moreWe study the technique of photothermal microscopy by which we can detect single nano-objects by their absorption at room temperature. We optimize the sensitivity of this technique and demonstrate the first optical detection of a single molecule by its absorption at room temperature. Moreover, we combine photothermal, luminescence and scattering of individual nano-objects (organic dye nanoparticles and gold nanoparticles) at single-particle level to gain insight into their radiative and nonradiative properties. Single organic nanoparticles exhibit a complex excitation power-dependent luminescence quantum yield due to singlet-singlet or singlet-triplet annihilation, and their luminescence quantum yield can be as high as 10^(__2). In contrast to organic dye nanoparticles, gold nanoparticles yield very stable optical signals. Gold nanoparticles are also easily detectable by their photoluminescence. We find that the luminescence quantum yield of single gold nanoparticles is nearly independent of their volumes and can be as high as ~10^(-5) for nanorods with a plasmon resonance of ~650 nm. We further investigate the sensitivity of a single gold nanorod to an approaching dielectric surface. We show that the nanorod exhibits significant red-shift in its plasmon resonance wavelength for distances less than 400 nm pointing the way towards the possible application of nanorods as distance sensors. Show less
We combine optical trapping and far-field optical detection techniques in a novel approach to study single metal nanoparticles in solution. We demonstrate the first measurements of the acoustic... Show moreWe combine optical trapping and far-field optical detection techniques in a novel approach to study single metal nanoparticles in solution. We demonstrate the first measurements of the acoustic vibrations of single gold nanoparticles optically trapped in water, and find evidence for intrinsic damping mechanisms. Additionally, we explore the potential of single gold nanorods as ultra-small mechanical actuators: we quantify the optical forces and torques on a single trapped gold nanorod (25 nm diameter and 60 nm length) and show that the rod can simultaneously exert forces and torques that would be large enough to manipulate single (macro-) molecules. We developed techniques to measure the combined translational and rotational Brownian motion of a trapped nanorod. We determine the rod's heating by the trap beam and show that translational and rotational Brownian motion of a hot particle are described by different effective temperatures and viscosities. Show less
