Complex Organic Molecules (COMs) have been detected in objects across different stages of stellar evolution. Many of these COMs are expected to form on interstellar ice and transfer later to the... Show moreComplex Organic Molecules (COMs) have been detected in objects across different stages of stellar evolution. Many of these COMs are expected to form on interstellar ice and transfer later to the gas phase. However, due to the challenge of detecting and assigning molecules in interstellar ice observations, the only frozen COM that has been unambiguously identified is methanol. This scenario is about to change, as the exceptional capabilities of the James Webb Space Telescope (JWST) enable the observation of weak signatures of molecules in interstellar ice.This thesis has a main focus on laboratory studies to support interstellar ice observation with the JWST. The results of the spectroscopic characterization of three COMs, acetone, methylamine, and methyl cyanide mixed in interstellar ice analogs are presented in Chapters 3, 4, and 5, respectively. The potential of their absorption features to trace these species in JWST observations is also discussed. Chapter 6 presents a new experimental approach to studying morphological changes in frozen CO, which is important to understand its morphology in space. Chapter 7 presents a computational study that simulates the infrared spectra of small fullerenes (between 44-70 C atoms) and provides insights for future JWST searches for these molecules Show less
This Thesis shows discoveries in non-linear astrochemical kinetics as well as a deeper analysis of dark clouds chemistry. It is concluded that autocatalysis in interstellar gas-phase chemistry... Show moreThis Thesis shows discoveries in non-linear astrochemical kinetics as well as a deeper analysis of dark clouds chemistry. It is concluded that autocatalysis in interstellar gas-phase chemistry leads to bistability but when coupled with the gas-grain exchange of key species, the system can show Hopf bifurcation and lead to the appearance of complex chemical oscillations. The results and discussion of the five chapters allow further understanding of the chemical evolution in a gas phase system and in a gas-grain environment, providing better predictions to compare with future observations. Show less
We have conducted a full spectral line survey of the 3-13 micron region of two massive protostars, AFGL 2591 and AFGL 2136, for the first time at high spectral resolution. Utilising SOFIA/EXES... Show moreWe have conducted a full spectral line survey of the 3-13 micron region of two massive protostars, AFGL 2591 and AFGL 2136, for the first time at high spectral resolution. Utilising SOFIA/EXES observations, combined with ground based observations from TEXES and iSHELL, many transitions of HCN, C2H2, NH3, CS, CO and H2O are observed, with all species observed to be in absorption. High temperatures (600 K) and abundances (1-10e-6 w.r.t H) of each species are derived. In this thesis, I will present the new insights into the physical conditions and chemical composition of the disks that these absorption lines probe. In particular, hundreds of ro-vibrational transitions of H2O are detected with EXES towards each object, and are linked to a disk wind in AFGL 2591. Column density variations of HCN and C2H2 in bands that probe the same lower level, across different wavelengths, are also discussed, supporting the location of this gas in the circumstellar disk of these protostars. Finally emission lines of HCN are discussed towards MonR2 IRS 3 and are consistent with an origin in a circumstellar disk, or also possibly an expanding shell of gas, supported by P-Cygni profiles of CO lines. Show less
