This thesis presents new insights into the reduction of carbon dioxide to methane and ethylene on copper electrodes. This electrochemical process has great potential for the storage of surplus... Show moreThis thesis presents new insights into the reduction of carbon dioxide to methane and ethylene on copper electrodes. This electrochemical process has great potential for the storage of surplus renewable electrical energy in the form of hydrocarbons. The research described in this thesis focuses on the molecular reaction mechanism, to identify key intermediates that determine the product selectivity. Show less
The primary goal of this thesis is to study the potential role of electrochemistry in finding new routes for sustainable chemicals from biomass in aqueous-phase solutions. In order to assess the... Show moreThe primary goal of this thesis is to study the potential role of electrochemistry in finding new routes for sustainable chemicals from biomass in aqueous-phase solutions. In order to assess the potential of electrochemistry in biomass conversion, we developed an online HPLC system by using a fraction collector with a micrometer-sized sampling tip placed close to the working electrode, with the collected sample fractions subsequently analyzed in an offline HPLC system. To demonstrate this method, we applied it to the poly-ols, i.e. glycerol (C3H8O3), electro-oxidation on Au and Pt electrodes at different pH conditions, visualizing the concentration changes of glycerol and its reaction products in correspondence with the current measured in voltammetry, which brought us a concept to co-generate hydrogen and valuable chemicals (i.e. glyceraldehyde, glyceric acid, dihydroxyacetone, formic acid) with high selectivity depending on the applied potential. In addition, we aimed at single-cell synthesis of sorbitol from cellulosic material by generating glucose as an intermediate species. This thesis has demonstrated the separate reactions of cellobiose hydrolysis to glucose by acid and hydroxyl radical on an anode and glucose hydrogenation to sorbitol on a cathode in an electrolysis cell. Show less
