High resolution solar spectra obtained from the ATMOS Fourier Transform Spectrometer (Spacelab 3 flight on April 29 - May 6, 1985) made it possible to detect for the first time vibration-rotation... Show moreHigh resolution solar spectra obtained from the ATMOS Fourier Transform Spectrometer (Spacelab 3 flight on April 29 - May 6, 1985) made it possible to detect for the first time vibration-rotation lines of NH from the X3 Sigma(-) state near 3 microns. Using recent theoretical results for the transition probabilities of 23 selected measured lines of the 1-0 and 2-1 bands, a solar abundance of nitrogen of 8.06 + or - 0.07 is derived. This value is compared with the result derived from N I lines and agrees with the abundance obtained from the 3s-3p, 3p-3d and 3s-prime - 3p-prime transitions, A(N) = 8.00 + or - 0.09. The final recommended solar abundance of nitrogen is A(N) = 8.00 + or - 0.05. Show less
The statistical equilibrium equations that determine the population densities of the energy levels in cometary C2 molecules due to fluorescent excitation are examined in detail. The adopted model... Show moreThe statistical equilibrium equations that determine the population densities of the energy levels in cometary C2 molecules due to fluorescent excitation are examined in detail. The adopted model and molecular parameters are discussed, and a theoretical estimate is made of the two intercombination transition moments. From the theoretical population densities in the various rotational levels, flux ratios and synthetic emission profiles are calculated as functions of the a 3Pi(u) - X 1Sigma(g)+ and the c 3Sigma(u)+ - X 3Sigma(g)+ intercombination transition moments. The influence of each of these two transitions separately on the vibrational and rotational excitation temperatures is investigated. The observed emission spectra of the (0,0) Swan band in Comet Halley are presented and compared to the synthetic profiles. Show less
Grevesse, N.; Sauval, A.J.; Dishoeck, E.F. van 1984
High resolution solar spectra have permitted the measurement with great accuracy of equivalent widths of vibration-rotation lines of OH in the X2Pi state near 3-micron wavelength. Using recent... Show moreHigh resolution solar spectra have permitted the measurement with great accuracy of equivalent widths of vibration-rotation lines of OH in the X2Pi state near 3-micron wavelength. Using recent theoretical results for the transition probabilities, a solar oxygen abundance of (8.93 + or - 0.02) is derived which is in perfect agreement with the abundance deduced from the OH pure rotation lines. The solar abundance of oxygen is therefore A(O) = 8.92 + or - 0.035, as inferred from the analysis of 43 vibration-rotation lines and 81 pure rotation lines of the OH molecule. It is confirmed that the dipole moment function of Werner, Rosmus and Reinsch (1983) together with the Holweger-Mueller (1974) solar atmosphere model are to be preferred in the analysis of the data. Show less