A dense region of a gaseous and dusty cloud collapses to form a protostar surrounded by a disk and an envelope. This thesis uses both observations and models to study physical and chemical... Show moreA dense region of a gaseous and dusty cloud collapses to form a protostar surrounded by a disk and an envelope. This thesis uses both observations and models to study physical and chemical conditions of these protostellar systems which are likely where planets start to form. From the observational side, ALMA is used to quantify abundance ratios of complex organic molecules (COMs) in the gas around young protostars. These ratios are found to be remarkably constant for various nitrogen-bearing COMs which points to formation of these molecules under similar conditions, likely in ices of the prestellar phase. Moreover, observations of JWST are used to tentatively detect molecules such as methyl cyanide and ethyl cyanide in interstellar ices for the first time. In addition, high angular resolution ALMA observations of a protostellar system are analyzed to report the first detection of a disk wind candidate in methanol and hydrogen cyanide. From the modeling side, radiative transfer models are used to investigate how physical conditions such as source structure can change the molecular emission and molecular abundances. These models show that disk and optically thick dust can decrease the emission from COMs and change the correlations among their column densities. Show less
Context. As material from an infalling protostellar envelope hits the forming disk, an accretion shock may develop which could (partially) alter the envelope material entering the disk.... Show moreContext. As material from an infalling protostellar envelope hits the forming disk, an accretion shock may develop which could (partially) alter the envelope material entering the disk. Observations with the Atacama Large Millimeter/submillimeter Array (ALMA) indicate that emission originating from warm SO and SO2 might be good tracers of such accretion shocks.Aims. The goal of this work is to test under what shock conditions the abundances of gas-phase SO and SO2 increase in an accretion shock at the disk-envelope interface.Methods. Detailed shock models including gas dynamics were computed using the Paris-Durham shock code for nonmagnetized J-type accretion shocks in typical inner envelope conditions. The effect of the preshock density, shock velocity, and strength of the ultraviolet (UV) radiation field on the abundance of warm SO and SO2 is explored. Compared with outflows, these shocks involve higher densities (similar to 10(7) cm(-3)), lower shock velocities (similar to few km s(-1)), and large dust grains (similar to 0.2 mu m) and thus probe a different parameter space.Results. Warm gas-phase chemistry is efficient in forming SO under most J-type shock conditions considered. In lower-velocity (similar to 3 km s(-1)) shocks, the abundance of SO is increased through subsequent reactions starting from thermally desorbed CH4 toward H2CO and finally SO. In higher velocity (greater than or similar to 4 km s(-1)) shocks, both SO and SO2 are formed through reactions of OH and atomic S. The strength of the UV radiation field is crucial for SO and in particular SO2 formation through the photodissociation of H2O. Thermal desorption of SO and SO2 ice is only relevant in high-velocity (greater than or similar to 5 km s(-1)) shocks at high densities (greater than or similar to 10(7) cm(-3)). Both the composition in the gas phase, in particular the abundances of atomic S and O, and in ices such as H2S, CH4, SO, and SO2 play a key role in the abundances of SO and SO2 that are reached in the shock.Conclusions. Warm emission from SO and SO2 is a possible tracer of accretion shocks at the disk-envelope interface as long as a local UV field is present. Observations with ALMA at high-angular resolution could provide further constraints given that other key species for the gas-phase formation of SO and SO2, such as H2S and H2CO, are also covered. Moreover, the James Webb Space Telescope will give access to other possible slow, dense shock tracers such as H-2, H2O, and [SI} 25 mu m. Show less
The thesis explores how interstellar chemistry evolves as a function of time and changing physical architectures during the formation of stars. The motivation behind the work is an aspiration to... Show moreThe thesis explores how interstellar chemistry evolves as a function of time and changing physical architectures during the formation of stars. The motivation behind the work is an aspiration to better understand how the Solar System came to be, which processes led to its chemical composition and ultimately, what enabled life to evolve on Earth. Show less
