Context. As material from an infalling protostellar envelope hits the forming disk, an accretion shock may develop which could (partially) alter the envelope material entering the disk.... Show moreContext. As material from an infalling protostellar envelope hits the forming disk, an accretion shock may develop which could (partially) alter the envelope material entering the disk. Observations with the Atacama Large Millimeter/submillimeter Array (ALMA) indicate that emission originating from warm SO and SO2 might be good tracers of such accretion shocks.Aims. The goal of this work is to test under what shock conditions the abundances of gas-phase SO and SO2 increase in an accretion shock at the disk-envelope interface.Methods. Detailed shock models including gas dynamics were computed using the Paris-Durham shock code for nonmagnetized J-type accretion shocks in typical inner envelope conditions. The effect of the preshock density, shock velocity, and strength of the ultraviolet (UV) radiation field on the abundance of warm SO and SO2 is explored. Compared with outflows, these shocks involve higher densities (similar to 10(7) cm(-3)), lower shock velocities (similar to few km s(-1)), and large dust grains (similar to 0.2 mu m) and thus probe a different parameter space.Results. Warm gas-phase chemistry is efficient in forming SO under most J-type shock conditions considered. In lower-velocity (similar to 3 km s(-1)) shocks, the abundance of SO is increased through subsequent reactions starting from thermally desorbed CH4 toward H2CO and finally SO. In higher velocity (greater than or similar to 4 km s(-1)) shocks, both SO and SO2 are formed through reactions of OH and atomic S. The strength of the UV radiation field is crucial for SO and in particular SO2 formation through the photodissociation of H2O. Thermal desorption of SO and SO2 ice is only relevant in high-velocity (greater than or similar to 5 km s(-1)) shocks at high densities (greater than or similar to 10(7) cm(-3)). Both the composition in the gas phase, in particular the abundances of atomic S and O, and in ices such as H2S, CH4, SO, and SO2 play a key role in the abundances of SO and SO2 that are reached in the shock.Conclusions. Warm emission from SO and SO2 is a possible tracer of accretion shocks at the disk-envelope interface as long as a local UV field is present. Observations with ALMA at high-angular resolution could provide further constraints given that other key species for the gas-phase formation of SO and SO2, such as H2S and H2CO, are also covered. Moreover, the James Webb Space Telescope will give access to other possible slow, dense shock tracers such as H-2, H2O, and [SI} 25 mu m. Show less
Chemistry plays an important role in the study of the physics and evolution of the warm dense Interstellar Medium (ISM). This is found in very different environment, e.g. in the disks around low... Show moreChemistry plays an important role in the study of the physics and evolution of the warm dense Interstellar Medium (ISM). This is found in very different environment, e.g. in the disks around low-mass young stellar objects (YSOs), in the envelopes of massive-YSOs, and in the nuclei of Ultra Luminous Infrared Galaxies (ULIRGS). The excitation temperatures and abundances of the observed molecules provide the observer with a physicochemical snapshot of the regions. The abundances of the molecules depend strongly on temperature, density, radiation field (UV, Infrared, and X-ray) and initial composition of the gas. Infrared spectroscopy is instrumental in the study of dense ISM as many species have transitions in the infrared. Space based instruments, unhindered by the earth atmosphere, allow us to study these. The absorption and emission features are often weak. Therefore a major challenge in using these instruments is to understand the instrumental characteristics and translating that knowledge into usable reduction algorithms. Most of the data used in this thesis are obtained with space based spectrographs, ISO-SWS and Spitzer-IRS, pushing them to their limits. Show less
