The primary focus of this thesis is the formation of low-mass protostars, specifically the earliest deeply embedded phase, when material from the collapsing envelope is still accreted onto the... Show moreThe primary focus of this thesis is the formation of low-mass protostars, specifically the earliest deeply embedded phase, when material from the collapsing envelope is still accreted onto the growing young star. Rotational transitions of CO and O2 data are obtained by the Herschel Space Observatory key projects, WISH and HOP, together with ground-based observations from APEX and the JCMT. We have found that CO and its isotopologs have different line profiles tracing different materials in the protostellar regions. Our new high-J rotational transitons of CO is key to characterize the warmer parts of the protostellar envelope and quantify feedback of the protostars on their surroundings in terms of shocks, ultraviolet (UV) heating, photodissociation, and outflow dispersal. Radiative transfer modeling was performed to determine the CO abundance structure in the envelope, showing evidence for significant freeze-out in the coldest regions in the parts of the envelope where the temperature exceeds 25 K. A tentative detection of O2 is reported toward the source position of a protostar, which originates from the surrounding cloud. These kind of detailed studies of the physical and chemical structure of low-mass protostars are important for a complete understanding of the evolution of young stellar objects (YSOs). Show less
The importance of ice in the interstellar medium is indisputable. Gas phase reactions relying on three-body collisions are exceedingly rare in the sparse medium between the stars. On solid surfaces... Show moreThe importance of ice in the interstellar medium is indisputable. Gas phase reactions relying on three-body collisions are exceedingly rare in the sparse medium between the stars. On solid surfaces, atoms and molecules can reside and rove the surface until a reaction takes place. Upon reaction, the released energy is dissipated into the grain, allowing the new species to form. Solid surfaces thus act as sites for chemical processes, that would otherwise be very slow, or not take place at all. This thesis is dedicated to the study of the composition and physical characteristics of interstellar ices using a variety of experimental observational techniques. The overall goal is to shed light on the processes that chemically enrich planet-forming regions. The specific objectives are to characterize morphological changes and molecular composition in interstellar ices, to explore new experimental techniques to study solid state reactions, and to use complex molecules to probe large scale astronomical phenomena. Show less
The different chapters cover studies in which the physical structures of the gas such as temperature, densities and movements of the gas are estimated. In addition chemical characteristics of the... Show moreThe different chapters cover studies in which the physical structures of the gas such as temperature, densities and movements of the gas are estimated. In addition chemical characteristics of the gas such as different molecular abundances and their spatial distribution are defined. This information is discussed in the context of how the chemical evolution of the gas in the planet-forming region progress and how this affects which type of planets that can form there. The results are mainly based on infrared observations and radiative transfer disk models. Show less
It has been a long standing problem in astrochemistry to explain how molecules can form in a highly dilute environment as the interstellar medium. In recent years it has become clear that solid... Show moreIt has been a long standing problem in astrochemistry to explain how molecules can form in a highly dilute environment as the interstellar medium. In recent years it has become clear that solid state reactions on icy grains play an important role in the formation of both simple and rather complex molecules. Laboratory based experiments that simulate the UV processing or the impact of H-atoms on interstellar ice analogues are needed in order to investigate the underlying processes. This is the topic of this PhD thesis that mainly summarizes research on SURFRESIDE, one of the ultra-high vacuum setup in the Sackler Laboratory for Astrophysics. It is shown how under fully controlled conditions molecules form when CO and O2 containing ices are bombarded by hydrogen atoms. Surface reaction schemes for methanol, water, carbon dioxide and formic acid formation at low temperatures in space are presented, and it is discussed how species may be chemically linked in space. Show less
Stars like our Sun are formed in large, tenuous clouds of gas and dust. As the star is formed at the centre, the remaining material collapses into a thick disk around it. The chemical composition... Show moreStars like our Sun are formed in large, tenuous clouds of gas and dust. As the star is formed at the centre, the remaining material collapses into a thick disk around it. The chemical composition of such a cloud changes dramatically during this process. Spherical models have always been used to model this chemical evolution, but they cannot properly describe the disk. This thesis presents the first model that follows the entire chemical evolution from a pre-stellar core to a circumstellar disk in two spatial dimensions. It follows material as it falls in from the cloud to the star and disk. The density, temperature and UV flux along these trajectories serve as input for a gas-phase chemical network -- including freeze-out onto and evaporation from cold dust grains. The model offers new insights into the chemical history of disks, in particular of the region where planets and comets are formed. Applications of the model include the gas/ice ratios of carbon monoxide and water (Chapter 2), the abundances of key gas-phase molecules (Chapter 3), the crystallinity of the dust (Chapter 4), the isotope-specific photodissociation of carbon monoxide (Chapter 5) and the charge balance of polycyclic aromatic hydrocarbons (PAHs; Chapter 6). Show less
During solar-type star formation, the chemistry evolves towards the formation of complex organic molecules, eventually setting the stage for the origin of life. This astrochemical evolution depends... Show moreDuring solar-type star formation, the chemistry evolves towards the formation of complex organic molecules, eventually setting the stage for the origin of life. This astrochemical evolution depends on the interaction between gas and microscopic interstellar grains, producing icy grain mantles. This thesis combines ice and gas-phase observations with astrophysically relevant laboratory simulations to constrain some of the key gas-grain processes. From Spitzer observations, the first simple ices, e.g. water and methane, form sequentially through condensation followed by an active surface chemistry, with more source-to-source variation the later in the sequence an ice forms. Close to the protostar the ices are heated. Experiments and their modeling have provided a generalized, quantitative understanding of the induced ice mixture evaporation and segregation, based on relative diffusion barriers alone. When no heat is available UV-induced evaporation still connects the ice and gas; UV photodesorption is found experimentally to be efficient with a similar yield for most ices. UV irradiation also converts simple ices into more complex species and this formation process has been quantified in situ for the first time. Based on these experiments, observations of complex organic molecules around protostars and in comets are readily explained by ice photochemistry. Show less
Stars form as a result of gravitational collapse of an interstellar molecular cloud. In the process, a circumstellar disk, often referred to as a protoplanetary disk, is formed as well as a result... Show moreStars form as a result of gravitational collapse of an interstellar molecular cloud. In the process, a circumstellar disk, often referred to as a protoplanetary disk, is formed as well as a result of the net angular momentum of the parental cloud. This thesis addresses several questions about the formation of this disk and, in particular, the evolution of the velocity field surrounding the young star. The composition of the velocity field (i.e., the ratio of infall to rotation) can be use to trace the evolution of young stellar objects. This method of characterizing the evolutionary stage of protostars is applied to two objects, NGC1333-IRAS2A and L1489 IRS, the first of which we find to be a very young object while the latter is significantly more evolved. In addition, one chapter of this thesis presents a new radiation transfer code which has been developed by the author. Show less
The formation of complex organic molecules that consist of more than four atoms in space is one of the main questions in the field of astrochemistry and star formation. Although the exact formation... Show moreThe formation of complex organic molecules that consist of more than four atoms in space is one of the main questions in the field of astrochemistry and star formation. Although the exact formation mechanisms are not yet known, they are expected to form in thin ice layers on the surfaces of small interstellar dust grains through successive addition of H, C, N or O atoms to CO (carbon monoxide). In this thesis the formation of these molecules is studied in two different ways: simulation of interstellar ices analogues in the laboratory and observations of the same molecules after evaporation toward star forming regions. The laboratory experiments are high and ultra high vacuum setups in which ices of e.g. CO, CO2, HCOOH and CH3CHO are frozen out on an inert surface. The spectroscopy and the thermal behavior of pure and layered ices have been studied. Furthermore, the ices have been bombarded with H-atoms to test reactions schemes relevant for astronomical environments. In the second part of this thesis the same molecules have been observed with the single dish submillimeter telescopes the __James Clerk Maxwell Telescope__ at Hawaii and the Institut de Radioastronomie Millim_trique in Spain toward a sample star forming regions as well as with interferometer the SubMillimeter Array at Hawaii toward two sources. The relative abundances of molecules in different star forming regions measured with the single dish telescopes as well as the spatial extent of the emission detected with the interferometer has been used to determine the chemical relations between complex organics that have also been studied in the laboratory. Show less
In this thesis we study the dust around solar-type young stars. In particular, we focus on one specific species of dust, namely the Polycyclic Aromatic Hydrocarbons (PAHs), a family of large... Show moreIn this thesis we study the dust around solar-type young stars. In particular, we focus on one specific species of dust, namely the Polycyclic Aromatic Hydrocarbons (PAHs), a family of large molecules, or small grains, that are widely observed in nearby star-forming regions. We address the following questions. What happens to PAHs in the embedded phase of a forming star? Are PAHs present in low-mass young star systems? Does the PAH emission originate from the envelope or from the disk? What do they tell us about disk structure and evolution and grain growth? What can we say about the evolution of PAHs during star formation and their typical size? We present mid-infrared spectroscopy and imaging surveys combined with 3D radiative transfer models to constrain the presence and location of PAH emission toward embedded young stellar objects and circumstellar disks around young solar-type stars. PAHs are detected toward a small fraction (11-14%) of young solar-type stars with disks and toward a minority of embedded objects (<3%), with derived abundances of 10-100 times lower than standard interstellar values. A new class of disks with weak mid-IR continuum emission and very strong PAH features is found. Show less
Planets form in disks of gas and dust around young stars. Since the gas makes up 99 % of the disk mass, it is critical for our understanding of planet formation to gain direct information from the... Show morePlanets form in disks of gas and dust around young stars. Since the gas makes up 99 % of the disk mass, it is critical for our understanding of planet formation to gain direct information from the gas, independently of what can be learned from dust emission. In this thesis, calculations are presented of the chemistry and gas temperature in disks, and the resulting atomic and molecular emission lines are investigated. The main focus of the thesis is on the effects of dust settling on gas-phase emission lines of disks around T-Tauri and Herbig Ae stars. It is found that dust settling has little effect on the overall chemistry and molecular lines; the main effect is a decrease in the gas temperature, which is reflected in atomic fine-structure lines and especially in the [O I] lines. The chemistry, and especially the CO abundance and HCN/CN ratio, is affected more by the total gas mass than by the dust gas ratio in a disk. The models were also applied to the disk around HD 141569A, which is in a transitional stage between a gas-rich Herbig Ae disk and a debris disk. Using chemical models to fit the observed CO rotational lines it is concluded that gas and small dust particles have an approximately interstellar mass ratio, and that gas is still present in the inner hole in the dust distribution Show less
The formation of snow and ice has always intrigued humans and challenged them to study these phenomena. Every snowflake has its own unique history of formation, but no two are alike. Like snow... Show moreThe formation of snow and ice has always intrigued humans and challenged them to study these phenomena. Every snowflake has its own unique history of formation, but no two are alike. Like snow-crystals, interstellar ices consist predominantly of water (H2O), but also contain significant fractions of other molecules such as carbon monoxide (CO), carbon dioxide (CO2), and methanol (CH3OH), and traces of dinitrogen (N2) and ammonia (NH3). The presence, or absence, of a molecule in the ice strongly depends on the environmental conditions. Vice versa, these molecules have an influence on their environment as well. Hence, the chemical composition and the structure of interstellar ices are thought to contain valuable information about the past and the future of interstellar regions, and it is for this reason that interstellar ices are simulated and studied under laboratory conditions. The present thesis contains a study of laboratory analogs of interstellar ices and presents a newly developed apparatus that provides a novel laboratory route to investigate the properties of these ices in more detail than has previously been possible. Show less
