This thesis is an experimental study of the UV irradiation of the interstellar ice analogues, relevant for the different stages of the star and planet formation sequence. It describes in detail... Show moreThis thesis is an experimental study of the UV irradiation of the interstellar ice analogues, relevant for the different stages of the star and planet formation sequence. It describes in detail photodesorption and photoconversion processes, and as such, contributes to worldwide efforts that aim at understanding how chemistry in space could have contributed to the origin of life on Earth and possibly planets around other stars. Show less
This thesis takes steps toward understanding the interaction between gas-phase and solid-state molecules in star- and planet-forming regions. Chapter 1 and 2 provide the reader with an introduction... Show moreThis thesis takes steps toward understanding the interaction between gas-phase and solid-state molecules in star- and planet-forming regions. Chapter 1 and 2 provide the reader with an introduction and in-depth description of methods used in subsequent chapters. Chapter 3 and 4 present the spectroscopic infrared characterization of acetaldehyde, dimethyl ether, ethanol, and methyl formate in the solid state, both pure and mixed in astronomically relevant matrices. This characterization will allow for probing of the solid-state organic inventory of star- and planet-forming regions with the upcoming James Webb Space Telescope. Interferometric observations of the protoplanetary disk around TW Hya with the Atacama Large Millimeter/submillimeter Array are presented in Chapter 5. These results hint that the observed gas-phase formaldehyde is formed in the gas phase, contrary to the generally accepted solid-state formation. Chapter 6 provides an insight to the interaction between gas-phase carbon monoxide and solid-state hydroxyl radicals on the surface of vacuum-UV irradiated water ice. Even tough residence times of carbon monoxide are short, they are sufficient to allow reactions with hydroxyl radicals and produce carbon dioxide. This process could explain the lack of gas-phase carbon monoxide in protoplanetary disks and the presence of carbon dioxide mixed in solid-state water. Show less
Le Gal, R.; Öberg, K.I.; Teague, R.; Loomis, R.A.; Law, C.J.; Walsh, C.; ... ; Zhang, K. 2021
Organic molecules in interstellar space are important as they influence the structure of galaxies and star formations. Studying catalytic processes in space allows us to understand how molecular... Show moreOrganic molecules in interstellar space are important as they influence the structure of galaxies and star formations. Studying catalytic processes in space allows us to understand how molecular species are formed and chemically evolved in the interstellar medium and solar system objects. Quantum chemical methods, such as “Density Functional Theory” (DFT), can be employed to study the chemical pathways for the formation of molecular species, which is challenging with only observations and experiments. This thesis studies, with DFT methods, how polycyclic aromatic hydrocarbons (PAHs), the most abundant organic species in space, catalyze the formation of molecular hydrogen in the interstellar medium. Specifically, how linear PAHs become superhydrogenated and how the presence of Stone Wales defect in PAHs contributes to their catalytic activity for molecular hydrogen formation. In addition, this thesis reports the study of the catalytic activity of forsterite, a silicate mineral abundant in grains, asteroids, and meteorites. Specifically, the presence of Schottky MgO vacancy in forsterite can catalyze the C-H activation of PAHs as the first step to study the breakdown reaction of PAHs in asteroidal settings. The latter is indispensable to understand the formation of the so-called organic inventory of solar system objects. Show less
The focus of this thesis is how stars like our Sun and planets like Jupiter, Saturn, and Earth are formed. With arrays of radio telescopes, I observed the environments where the first stages of... Show moreThe focus of this thesis is how stars like our Sun and planets like Jupiter, Saturn, and Earth are formed. With arrays of radio telescopes, I observed the environments where the first stages of star and planet formation occur. This thesis focuses on characterizing different components of young protostellar systems, most notably their jets and disks. Using interferometric radio observations with ALMA array, I provided information on key chemical tracers of different components of the protostellar systems. By characterizing the radio signal from young stars with ALMA and VLA interferometers, I was able to disentangle an emission from the jet and the disk. This led to an unexpected development: I was able to compare dust masses of young disks with those of older disks for the first time. By comparing this information with masses of the extrasolar planets detected so far I showed that the solid cores of gas giants must form in the first 0.1 Myr of stellar life. That is an important time constrain, that pushes the onset of planet formation earlier and highlights the importance of characterization of the youngest protostars in understanding the origin of Solar System and Earth. Show less
