Stars like the sun are born in large molecular clouds existing from gas and dust. During the formation process, the chemical composition of the material can be altered drastically by the changing... Show moreStars like the sun are born in large molecular clouds existing from gas and dust. During the formation process, the chemical composition of the material can be altered drastically by the changing physical conditions. This thesis focuses on how molecules in young protostellar systems are inherited from molecular clouds. The emphasis lies on so-called complex organic molecules and accretion shocks.Based on observations of complex organic molecules, it can be suggested that the molecular composition of a protostellar disk is (partially) inherited from the molecular cloud. The abundance ratio between various molecules is remarkably constant in various protostellar systems, implying that they form under similar conditions in molecular clouds. Furthermore, absence of complex molecules in observations does not directly mean that they are absent in the protostellar system but rather that they are hidden from us.This thesis also focuses on accretion shocks at the boundary between infalling cloud and protostellar disk. Based on a comparison between detailed numerical simulations and observations it can be suggested that strong accretions are not always present in protostellar systems. In turn, this suggests that the chemical composition in protostellar disks can be directly inherited from the molecular cloud. Show less
This Thesis shows discoveries in non-linear astrochemical kinetics as well as a deeper analysis of dark clouds chemistry. It is concluded that autocatalysis in interstellar gas-phase chemistry... Show moreThis Thesis shows discoveries in non-linear astrochemical kinetics as well as a deeper analysis of dark clouds chemistry. It is concluded that autocatalysis in interstellar gas-phase chemistry leads to bistability but when coupled with the gas-grain exchange of key species, the system can show Hopf bifurcation and lead to the appearance of complex chemical oscillations. The results and discussion of the five chapters allow further understanding of the chemical evolution in a gas phase system and in a gas-grain environment, providing better predictions to compare with future observations. Show less
We have conducted a full spectral line survey of the 3-13 micron region of two massive protostars, AFGL 2591 and AFGL 2136, for the first time at high spectral resolution. Utilising SOFIA/EXES... Show moreWe have conducted a full spectral line survey of the 3-13 micron region of two massive protostars, AFGL 2591 and AFGL 2136, for the first time at high spectral resolution. Utilising SOFIA/EXES observations, combined with ground based observations from TEXES and iSHELL, many transitions of HCN, C2H2, NH3, CS, CO and H2O are observed, with all species observed to be in absorption. High temperatures (600 K) and abundances (1-10e-6 w.r.t H) of each species are derived. In this thesis, I will present the new insights into the physical conditions and chemical composition of the disks that these absorption lines probe. In particular, hundreds of ro-vibrational transitions of H2O are detected with EXES towards each object, and are linked to a disk wind in AFGL 2591. Column density variations of HCN and C2H2 in bands that probe the same lower level, across different wavelengths, are also discussed, supporting the location of this gas in the circumstellar disk of these protostars. Finally emission lines of HCN are discussed towards MonR2 IRS 3 and are consistent with an origin in a circumstellar disk, or also possibly an expanding shell of gas, supported by P-Cygni profiles of CO lines. Show less
