Concomitant dimorphism in poly[di-μ-azido-(5,5′-dimethyl-2,2′-bipyridine)iron(II)]

Setifi, Z.; Bernès, S.; Geiger, D.K.; Setifi, F.; Reedijk, J. (2022)

Article / Letter to editor

The title metal-organic polymer, catena-poly[[(5,5'-dimethyl-2,2'-bipyridine-κ²N,N')iron(II)]-di-μ-azido-κ²N¹:N³-[(5,5'-dimethyl-2,2'-bipyridine-κ²N,N')iron(II)]-di-μ-azido-κ²N¹:N¹], [Fe(N₃)₂(C₁₂H₁₂N₂)]_n, features alternating μ-1,1 (end-on mode of coordination) and μ-1,3 (end-to-end mode of coordination) double azide bridges, forming chains running in the [100] direction. The octahedral coordination geometry around the Fe^II centre is completed by a bidentate 5,5'-dimethyl-2,2'-bipyridine ligand. Two polymorphs for this compound were obtained from the crude reaction product, the first in the space group P-1 and the other in P2₁/c. The molecular and crystal structures are very similar for both forms, the main difference being that the eight-membered Fe(μ-1,3-N₃)₂Fe metallacycle formed with end-to-end azide ligands has a nearly flat conformation in the triclinic form and a chair conformation in the monoclinic form. In spite of this geometric difference, both forms have the same density, the same packing index and similar arrangements of the one-dimensional chains in the crystal. As a consequence, they also share very similar Hirshfeld surfaces and fingerprint plots. However, a density functional theory (DFT) computational study showed that the monoclinic form is more stable than the triclinic form by ca 30.5 kJ mol^-1.

• All authors: Setifi, Z.; Bernès, S.; Geiger, D.K.; Setifi, F.; Reedijk, J.
• Date: 2022-07-21
• Journal: Acta Crystallographica Section C: Structural Chemistry
• Volume: 78
• Issue: 8
• Pages: 449 - 454
• DOI: doi:10.1107/S2053229622006908