Measurements were carried out on the CO J = 3-2 emission line at 345 GHz from a number of translucent and high-latitude molecular clouds, as well as on the J = 2-1 and J = 1-0 lines of both the (C... Show moreMeasurements were carried out on the CO J = 3-2 emission line at 345 GHz from a number of translucent and high-latitude molecular clouds, as well as on the J = 2-1 and J = 1-0 lines of both the (C-12)O and (C-13)O. It is shown that the physical conditions in the high-latitude clouds are very similar to those in the translucent clouds. The densities derived from measured (C-12)O 1-0/3-2 ratios were often found to be higher than those based on the C2 excitation, while densities derived from measured 3-2/(C-13)O 1-0 ratios were similar to those based on C2. Show less
The CS J = 2-1 emission line at 98 GHz has been searched for in 10 diffuse molecular clouds. CS column densities are derived by performing statistical equilibrium calculations for the rotational... Show moreThe CS J = 2-1 emission line at 98 GHz has been searched for in 10 diffuse molecular clouds. CS column densities are derived by performing statistical equilibrium calculations for the rotational population distribution which includes collisional excitation by electrons as well as by neutral species. Because CS has a large dipole moment, the electron collisions completely dominate the CS excitation in diffuse clouds, where the electron fraction is high. This result suggests that, in general, molecules with large dipole moments may be relatively more detectable by millimeter emission in diffuse clouds than in dense clouds. A detailed model of the gas-phase sulfur chemistry in diffuse clouds is developed to interpret the observations. Show less
Optical absorption-line techniques have been applied to the study of a number of translucent molecular clouds in which the total column densities are large enough that substantial molecular... Show moreOptical absorption-line techniques have been applied to the study of a number of translucent molecular clouds in which the total column densities are large enough that substantial molecular abundances can be maintained. Results are presented for a survey of absorption lines of interstellar C2, CH, and CN. Detections of CN through the A 2Pi-X 2Sigma(+) (1,O) and (2,O) bands of the red system are reported and compared with observations of the violet system for one line of sight. The population distributions in C2 provide diagnostic information on temperature and density. The measured column densities of the three species can be used to test details of the theory of molecule formation in clouds where photoprocesses still play a significant role. The C2 and CH column densities are strongly correlated with each other and probably also with the H2 column density. In contrast, the CN column densities are found to vary greatly from cloud to cloud. The observations are discussed with reference to detailed theoretical models. Show less
Recent high-resolution observations of interstellar absorption lines of CH and CN toward Zeta Oph obtained by Crane et al. (1986), and Palazzi et al. (1988), exhibit line widths that suggest... Show moreRecent high-resolution observations of interstellar absorption lines of CH and CN toward Zeta Oph obtained by Crane et al. (1986), and Palazzi et al. (1988), exhibit line widths that suggest thermal line broadening at high temperature, T about 1200 K. Observations of CO line emission at 2.6 mm toward Zeta Oph (Langer et al.,1987) indicate that the molecular gas resides in four distinct velocity components that span less than 3 km/s in Doppler velocity. Simulated CH and CN absorption line profiles are compared for high-temperature (T = 1200 K) thermal broadening and for a combination of low-temperature (T = 50 K) thermal plus turbulent broadening. It is shown that the two broadening models reproduce existing observations comparably well and are virtually indistinguishable at a lambda/Delta-lambda ratio of about 100,000. The observed differences in the CH and CN line widths may reflect slightly different distributions of those molecules along the line of sight. The simulations use very recent, improved laboratory spectroscopic data on CH (Bernath). Some related consequences of such unresolved velocity structure on the ultraviolet absorption lines of CO are examined. Indirect diagnostics of temperature in the Zeta Oph cloud favor low-temperature thermal plus turbulent broadening, and the implied rate of dissipation of turbulence is in harmony with estimates of the global input of mechanical energy into to interstellar medium. Show less
Interstellar absorption lines of CH and CH(+) have been detected toward the star HD 210121, which is located behind a previously unknown high-latitude cloud. The CH observations and the measured... Show moreInterstellar absorption lines of CH and CH(+) have been detected toward the star HD 210121, which is located behind a previously unknown high-latitude cloud. The CH observations and the measured extinction toward the star provide independent measures of the H2 column density along the line of sight, which are compared with that deduced from CO mm observations. The inferred CH(+) column density is comparatively small, suggesting that shocks do not play a dominant role in the chemistry in the cloud. Show less
Jannuzi, B.T.; Black, J.H.; Lada, C.J.; Dishoeck, E.F. van 1988
Optical absorption line observations of the B1 supergiant HD 169454 reveal the presence of an intervening translucent interstellar cloud. Millimeter wavelength observations of CO emission show that... Show moreOptical absorption line observations of the B1 supergiant HD 169454 reveal the presence of an intervening translucent interstellar cloud. Millimeter wavelength observations of CO emission show that the absorption lines can be attributed to a well-defined cloud approximately 18 by 22 min in extent at the same radial velocity as the C2 and CN absorption lines. The map of the CO emission shows three large condensations and evidence of unresolved structure on smaller scales. Various procedures for determining the cloud mass are compared. The estimated mass is 7-14 M solar masses if the cloud lies at the distance (D about 125 pc) of an extended atomic cloud at the same radial velocity, and is 250-500 M solar masses if the kinematic distance (D about 750 pc) is adopted. The dynamical state of the cloud is examined. The composition and structure of the cloud are discussed with reference to detailed theoretical models and the properties of other interstellar clouds. Show less
The effects of the presence of a substantial component of large molecules on the chemistry of diffuse molecular clouds are explored, and detailed models of the zeta Persei and zeta Ophiuchi clouds... Show moreThe effects of the presence of a substantial component of large molecules on the chemistry of diffuse molecular clouds are explored, and detailed models of the zeta Persei and zeta Ophiuchi clouds are constructed. The major consequence is a reduction in the abundances of singly charged atomic species. The long-standing discrepancy between cloud densities inferred from rotational and fine-structure level populations and from the ionization balance can be resolved by postulating a fractional abundance of large molecules of 1 x 10 to the -7th for zeta Persei and 6 x 10 to the -7th for zeta Ophiuchi. If the large molecules are polycyclic aromatic hydrocarbons (PAH) containing about 50 carbon atoms, they contain 1 percent of the carbon in zeta Persei and 7 percent in zeta Ophiuchi. Other consequences of the possible presence of PAH molecules are discussed. Show less
The infrared emission spectrum of H2 excited by ultraviolet absorption, followed by fluorescence, was investigated using comprehensive models of interstellar clouds for computing the spectrum and... Show moreThe infrared emission spectrum of H2 excited by ultraviolet absorption, followed by fluorescence, was investigated using comprehensive models of interstellar clouds for computing the spectrum and to assess the effects on the intensity to various cloud properties, such as density, size, temperature, and the intensity of the UV radiation field. It is shown that the absolute H2 IR line intensities depend primarily on the density of the cloud and the strength of the incident UV radiation, and to a much lesser exent on the temperature of the gas, the total thickness of the cloud, and the optical properties of the grains. A variety of recent observational results are discussed with reference to theoretical models. It is shown that the rich H2 emission spectrum of the reflection nebula NGC 2023 can be reproduced by a model with density of about 10,000/cu cm, temperature of about 80 K, and UV flux approximately 300 times that of the Galactic background starlight. Show less
The limitations of steady state models of interstellar clouds are explored by means of comparison with observational data corresponding to clouds in front of Zeta Per, Zeta Oph, Chi Oph, and... Show moreThe limitations of steady state models of interstellar clouds are explored by means of comparison with observational data corresponding to clouds in front of Zeta Per, Zeta Oph, Chi Oph, and Omicron Per. The improved cloud models were constructed to reproduce the observed H and H2(J) column densities for several lines of sight. The main difference from previous models is the treatment of self-shielding in the H2 lines. Other improvements over previous models are discussed as well. Show less
Observations of C2 in the (3,O) band around 7720 A toward Zeta Ophiuchi are presented and used to provide additional support for the suggestion of a low temperature in the center of the principal... Show moreObservations of C2 in the (3,O) band around 7720 A toward Zeta Ophiuchi are presented and used to provide additional support for the suggestion of a low temperature in the center of the principal cloud toward that star. Twelve absorption features belonging to the P, Q, and R branches and originating from levels up to J-double prime = 10 can be identified. Measured equivalent widths and the column densities obtained from them by assuming a linear relationship are presented. The column densities in the various rotational levels generally agree well with those found from observations of C2 in the (2,0) Phillips band around 8750 A. The observed C2 rotational distribution implies a low kinetic temperature of roughly 30 K and a relatively low but uncertain density of roughly 200/cm in the center of the cloud. Show less
Interstellar absorption lines of the C2 (2-0) Phillips band at 8750 A have been searched for in the spectra of southern stars. Seventeen lines originating from the lowest eight rotational levels... Show moreInterstellar absorption lines of the C2 (2-0) Phillips band at 8750 A have been searched for in the spectra of southern stars. Seventeen lines originating from the lowest eight rotational levels have been detected toward Chi Oph, and eleven lines originating from the lowest five rotational levels toward HD 154368 and 147889. No C2 lines were seen toward HD 149404. A recently developed theory has been used to extract information about the density, temperature or strength of the radiation field in the line-forming interstellar regions from the observed rotational populations. The results are compared with those obtained from other molecular observations. Toward Chi Oph, the interstellar radiation field appears enhanced in the ultraviolet part of the spectrum relative to the infrared part. The C2 data suggest a higher kinetic temperature for the material in front of HD 147889 than is inferred from radio observations. Show less
