Redox Interconversion between Cobalt(III) Thiolate and Cobalt(II) Disulfide Compounds

Author(s):
Jiang, F.; Siegler, M.A.; Sun, X.; Jiang, L. (0000-0002-8969-9078); Fonseca Guerra, C. (0000-0002-2973-5321); Bouwman, E. (0000-0001-7762-3968)
Published
2018
Publication type
Article / Letter to editor

Abstract

In contrast to cobalt, reaction of ligand

L1

SSL1 with [Fe(MeCN)6](BF4)2 did not yield the expected Fe(III) thiolate compound. This work is an unprecedented example of redox interconversion between a high-spin Co(II) disulfide compound and a low-spin Co(III) thiolate compound triggered by the nature of the anion.

Date issued
2018-08-06
Language
English
Is part of
Inorganic Chemistry (2018), Vol. 57, no. 15, p. 8796-8805
hdl
1887/67216
doi
10.1021/acs.inorgchem.8b00549